Currently, no. Nobody is home between 730-530 most days. They get grain and hay twice daily, sometimes if someone is home and its super cold(in which case they'll be in the barn) they'll get some for lunch. I am working on changing this, but my grandmother is extremely set in her ways and stubborn. She is adamant that this is how it needs to be done. However, she's done it this way for 20(?) Or so years, with no ill effects. I know better ways are available, but this is what works for us for the time being.
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That being said, I did morning/evening hay tossing and never had issue with it. It has only been within the last year that we've switched to the use of a round bale that enables them to have 24/7 access to hay. We would toss hay about 7 and again at 5 and the horses never showed any ill-effects.